The effective fragment model for solvation: Internal rotation in formamide

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The Effective Fragment Model for Solvation: Internal Rotation in Formamide

The internal rotation of formamide with 0–5 water molecules oriented along the N–C bond has been studied by the full ab initio self‐consistent field theory and using the effective fragment (EFP) method. For each case, the EFP geometries, harmonic vibrational frequencies, rotational barriers, and intrinsic reaction coordinates for the internal rotation are found to be in excellent agreement with...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 1996

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.472909